王晓明 研究员

中国科学院上海有机化学研究所 

金属有机化学国家重点实验室　 

上海市零陵路345号，200032 

电话: +86 21 54925578

邮箱:xiaoming@sioc.ac.cn 

网站: http://wangxgroup.sioc.ac.cn/

简介：

2019年3月：研究员，中科院上海有机所金属有机国家重点实验室 

2018年2月-2019年3月：博士后，日本东京大学工学院Kyoko Nozaki教授 

2014年9月-2018年1月：洪堡学者，博士后，德国明斯特大学Frank Glorius教授 

2009年9月-2014年7月：硕博研究生，中国科学院上海有机化学研究所 

2005年9月-2009年7月：理学学士，浙江大学 

 

研究领域：

针对均相和非均相金属催化中的重要科学问题，如金属间基团转移、电子传递的调控和规律、金属间的协同效应、金属的簇集和催化等，致力于研究多金属物种参与的反应体系，包括通过金属间电子传递、基团转移实现挑战性的转化过程和探究内在规律、仿酶的双多核金属催化剂的开发和金属团簇催化等。 

 

获奖及荣誉： 

2013年博士研究生国家奖学金 

2014年度中国科学院院长特别奖 

2015年度中国科学院优秀博士学位论文 

德国洪堡博士后奖学金 

2020年度“Thieme Chemistry Journals Award”国际学术奖 

 

代表性论文：

14. Yang, Y.#; Lu, B.#; Xu, G.*; Wang, X.*ACS Cent. Sci.2022,8, 581-589. Overcoming O-H Insertion to Para-Selective C-H Functionalization of Free Phenols: Rh(II)/Xantphos Catalyzed Geminal Difunctionalization of Diazo Compounds (#contributed equally to this work).

13.He, Y.; Wang, Y.; Li, S.J.; Lan, Y.*; Wang, X.*Angew. Chem. Int. Ed.2022, e202115497. Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes.

12. Zhao, F.#; Jiang, F.#; Wang, X.*Sci. China Chem.2022, 10.1007/s11426-022-1331-y. Deoxygenative Alkylation of Tertiary Amides Using Alkyl Iodides under Visible Light (#contributed equally to this work).

11.Jiang, F.#; Zhao, F.#; He Y.; Luo, X.; Wang, X.*Cell Rep. Phys. Sci.2022, 10.1016/j.xcrp.2022.100955. Efficient Synthesis of β-Substituted Amines via Combining Deoxygenation of Amides with Photochemical Organocatalysis (#contributed equally to this work).

10. Liu, T.#; Li, C.#; Bai, J.; Zhang, P.*; Guo, Y.*; Wang, X.*Chin. J. Chem.2022,40, 2203-2211. Markovnikov-Selective Hydroboration of Aryl Alkenes Enabled by a Simple Nickel Salt (#contributed equally to this work).

9.Zhang, J.#; Liu, T.#; Wang, L.*; Wang, X.*Chin. J. Org. Chem.2022, 10.6023/cjoc202203060. Recent Process in the In situ Generated Metal Nanocluster Catalysis(#contributed equally to this work, review, in Chinese).

8. Ma, S.; Li, F.; Zhang, G.*; Shi, L.*; Wang, X.*ACS Catal.2021,11, 14848-14853. Highly Regioselective Difluoroalkylarylation of Butadiene through a Nickel-Catalyzed Tandem Radical Process.

7.Chen, K.⊥; Zhu, H.⊥; Li, Y.; Peng, Q.*; Guo, Y.*; Wang, X.*ACS Catal.2021,11, 13696-13705. Dinuclear Cobalt Complex-Catalyzed Stereodivergent Semireduction of Alkynes: Switchable Selectivities Controlled by H2O (⊥contributed equally to this work).

6.Li, Z.; Zhao, F.; Ou, W.; Huang, P.-Q.*; Wang, X.*Angew. Chem. Int. Ed.2021,60, 26604-26609. Asymmetric Deoxygenative Alkynylation of Tertiary Amides Enabled by Iridium/Copper Bimetallic Relay Catalysis.

5.Song, S.; Li, C.; Liu, T.; Zhang, P.*; Wang, X.*Org. Lett.2021,23, 6925-6930. H-BPin/KOtBu Promoted Activation of Cobalt Salt to a Heterotopic Catalyst for Highly Selective Cyclotrimerization of Alkynes.

4. Lu, B.; Liang, X.; Zhang, J.; Wang, Z.; Peng, Q.*; Wang, X.*J. Am. Chem. Soc.2021,143, 11799-11810. Dirhodium(II)/Xantphos-Catalyzed Relay Carbene Insertion and Allylic Alkylation Process: Reaction Development and Mechanistic Insights.

3.Li, C.; Song, S.; Li, Y.; Xu, C.; Luo, Q.; Guo, Y.*; Wang, X.*Nat. Commun.2021,12, 3813-3820.Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst.

2.Jiao, J.; Wang, X.*Angew. Chem. Int. Ed.2021,60, 17088-17093. Merging Electron Transfer with 1,2-Metalate Rearrangement: Deoxygenative Arylation of Aromatic Amides with Arylboronic Esters.

1.He, Y.; Wang, X.*Org. Lett.2021,23, 225-230. Synthesis of Cyclic Amidines by Iridium-Catalyzed Deoxygenative Reduction of Lactams and Tandem Reaction with Sulfonyl Azides.