麻生明 （院士）

中国科学院上海有机化学研究所

金属有机化学国家重点实验室　

上海市零陵路345号，200032

电话: +86 21 54925147

传真: +86 21 64167510

邮箱: masm@sioc.ac.cn

教育：

1986.09 - 1990.12　 　中国科学院上海有机化学研究所，博士(导师：陆熙炎院士)

1982.09 - 1986.07　　 杭州大学化学系，学士

工作经历：

2007.10 -　　　　　华东师范大学，教授；中科院上海有机所特聘研究员，浙江大学和香港中文大学兼职教授

2003.02 - 2007.09　  中科院上海有机所与浙江大学共聘，国家重点实验室主任，研究员，长江特聘教授

1997.09 - 2003.02　  中国科学院上海有机化学研究，实验室主任，研究员

1997.03 - 1997.09　  中国科学院上海有机化学研究所，副研究员

1993.10 - 1997.03　  美国普渡大学(Purdue University)，博士后

1992.09 - 1993.10 　 瑞士苏黎世联邦理工大学(ETH)，博士后

1990.12 - 1992.09　 中国科学院上海有机化学研究所，助理研究员、副研究员

研究领域：
  • 金属有机化学
  • 自由基化学
  • 多步合成

获奖及荣誉：
  • 中国科学院优秀研究生指导教师奖 (2009)
  • 中国科学院优秀研究生指导教师奖 (2008)
  • 第三届中国化学会黄耀曾金属有机化学奖 (2008)
  • 2004-2006年度上海市劳动模范称号 (2007)
  • 中科院研究生院优秀教育工作者 (2006)
  • 国家自然科学二等奖(排名第一) (2006)
  • OMCOS-Springer  Award (2005)
  • 第五届上海市自然科学牡丹奖 (2004)
  • 上海市科技进步一等奖(排名第一) (2004)
  • 国家重点实验室计划先进个人 (2004)
  • 中国化学会有机化学专业委员会“有机合成创造奖” (2004)
  • Mr. and Mrs. Sun Chan Memorial Award in Organic Chemistry (2004)
  • 中国科学院优秀研究生指导教师 (2004)
  • 上海优秀留学回国人才 (2004)
  • 中国科学院优秀研究生导师奖 (2003)
  • 全国留学回国人员成就奖 (2003)
  • Young Scholar Travel Grant Award for the 2000 International Chemical Congress of Pacific Basin Societies, American Chemistry Society (2000)
  • 中国化学会青年化学奖 (1999)
  • 中国科学院十大杰出青年(1999)
  • 国家自然科学二等奖 (排名第二) (1999)
  • 求是基金杰出青年学者奖 (1999)
  • 中国科学院青年科学家奖一等奖 (1999)
  • 中国科学院自然科学一等奖(排名第二) (1997)
  • Research Accomplishments Award (1994)
  • 中科院院长奖学金特别奖 (1991)

代表论著：

1. Transition Metal-Catalyzed/Mediated Reaction of Allenes with A Nucleophilic Functionality Connected to the a-Carbon Atom Shengming Ma* Acc. Chem. Res. 2003, 36, 701-712.

 Electrophilic Addition and Cyclization Reactions of Allenes Shengming Ma Acc. Chem. Res. 2009, 42, 1679-1688. 

2. Some Typical Advances in the Synthetic Applications of Allenes Shengming Ma Chem. Rev. 2005, 105, 2829-2871.

3. Recent Adavances in the Chemistry of Allenes Shengming Ma Aldrichimica Acta 2007，(4), 91-102.

4. Pd(0)-catalyzed Insertion-Cyclization Reaction of 2,3-Allenols with Aryl or Alkenyl Halides. Diastereoselective Synthesis of Highly Optically Active trans-2,3-Disubstituted Vinylic Oxiranes Shengming Ma* and Shimin Zhao J. Am. Chem. Soc. 1999, 121, 7943.

5. Novel Substituent and Chelating Effects in the Pd-Catalyzed Reaction of 2,3-Allenols, Aryl Iodides, and Amines. Highly Regio- and Stereo-selective Synthesis of 2-Amino-3-alken-1-olsor 4-Amino-2(E)-alken-1-ols  Shengming Ma* and Shimin Zhao J. Am. Chem. Soc. 2001，123，5578.

6. Highly Regio- and Stereoselective Halohydroxylation Reaction of 1,2-Allenyl Phenyl Sulfoxides. Reaction Scope, Mechanism and the Corresponding Pd- or Ni-Catalyzed Selective Coupling Reactions Shengming Ma*, Hongjun Ren, and Qi Wei J. Am. Chem. Soc. 2003, 125, 4817-4830.

7. 2,3,4- or 2,3,5-Trisubstituted Furans: Catalyst-Controlled Highly Regioselectively Ring-Opening Cycloisomerization Reaction of Cyclopropenyl Ketones Shengming Ma* and Junliang Zhang J. Am. Chem. Soc. 2003, 125, 12386-12387.

8. A Novel X- (X=I, Br)-Triggered Ring-opening Coupling Reaction of Cyclopropenes with Organic Halides Shengming Ma*, Junliang Zhang, Yangjun Cai and Lianghua Lu J. Am. Chem. Soc. 2003, 125, 13954-13955.

9. Catalytic Regioselectivity Control in Ring-Opening Cycloisomerization of Methylene- or Alkylidenecyclopropyl Ketones Shengming Ma, Lianghua Lu, Junliang Zhang J. Am. Chem. Soc. 2004; 126, 9645-9660.

10. PdCl2-Catalyzed Two-Component Cross-coupling Cyclization of 2,3-Allenoic Acids and 2,3-Allenols. An Efficient Synthesis of 4-(1’, 3’-Dien-2’-yl)-2-furanone Derivatives Shengming Ma* and Zhenhua Gu J. Am. Chem. Soc. 2005, 127, 6182-6183.

11. ESI-MS Studies on the Mechanism of Pd(0)-Catalyzed Three-Component Tandem Double Addition-Cyclization Reaction Hao Guo, Rong Qian, Yuanxi Liao, Shengming Ma* and Yinlong Guo* J. Am. Chem. Soc. 2005, 127, 13060.

12. Sequential Rearrangement of 1,2,4Z,7-Tetraenes Involving [1,5]-Hydrogen Migration and Electrocyclization: An Efficient Synthesis of Eight-membered Cyclic Compounds Shengming Ma* and Zhenhua Gu J. Am. Chem. Soc. 2006, 128, 4942-4943.

13. Palladium Acetate-Catalyzed Cyclization Reaction of 2,3-Allenoic Acids in the Presence of Simple Allenes: An Efficient Synthesis of 4-(1’-Bromoprop-2’(Z)-en-2’-yl)furan-2(5H)-one Derivatives and the Synthetic Application Zhenhua Gu, Xinke Wang, Wei Shu, and Shengming Ma* J. Am. Chem. Soc. 2007, 129, 10948-10956.

14. trans-RhCl(CO)(PPh3)2-Catalyzed Monomeric and Dimeric Cycloisomerization of Propargylic 2,3-Dienoates. Establishment of α,β-Unsaturated δ-Lactone Rings by CyclometallationXuefeng Jiang and Shengming Ma* J. Am. Chem. Soc. 2007, 129, 11600-11607.

15. Iron-Catalyzed Highly Regio- and Stereoselective Conjugate addition of 2,3-Allenoates with Grignard Reagents Zhan Lu, Guobi Chai, Shengming Ma J. Am. Chem. Soc. 2007, 129, 14546-14547.

16. Novel Oxidative Cyclization/Dimerization Reaction of 2,3-Allenoic Acids and 1,2-Allenyl Ketones. An Efficient Synthesis of 4-(3’-Furanyl)butenolide Derivatives Shengming Ma* and Zhanqian Yu Angew. Chem. Int. Ed. 2002, 41, 1775.

17. Palladium(0)–Catalyzed Three-Component Tandem Double Addition-Cyclization Reaction: A Facile One–Pot Highly Chemo-, Regio- and Stereo-selective Synthesis of Cis-Pyrrrolidine Derivatives from 2-(2’,3’-Dienyl)malonates, Organic Halides, and Imines Shengming Ma* and Ning Jiao Angew. Chem. Int. Ed. 2002, 41, 4737-4740.

18. Tuning the Regioselectivity in Palladium(II)-Catalyzed Isomerization of Alkylidenecyclopropyl Ketones. A Dramatic Salt Effect Shengming Ma* and Junliang Zhang Angew. Chem. Int. Ed., 2003, 42, 183-187.

19. Tuning the Regioselectivity in the Coupling Reaction Involving Allenic/Propargylic Palladium Species. A Ligand Switch Shengming Ma* and Guanwei Wang Angew. Chem. Int. Ed. 2003, 42, 4215-4217.

20. Walking of C-C-p-Bond over Long Distances in Pd-Catalyzed Reactions of 2,3-Allenoic Acids with (w-1)-Alkenyl Halides Shengming Ma* and Zhanqian Yu Angew. Chem. Int. Ed. 2003, 42, 1955-1957.

21. A Novel 1,3-lithium Shift of Propargylic/Allenylic Lithium and the Subsequent Transmetalation/Coupling Reaction with Aryl Halides Shengming Ma* and Qiwen He Angew. Chem. Int. Ed. 2004, 43, 988-990.

22. Probing the Mechanism of Palladium-Catalyzed Addition of Organoboronic Acids to Allenes in the Presence of AcOH with ESI-FTMS　Rong Qian, Hao Guo, Yuanxi Liao, Yinlong Guo,* and Shengming Ma* Angew. Chem. Int. Ed. 2005, 44, 4771-4774.

23. What Can a Metal Catalyst Do with Allenes? One-Step Building Up of New Steroid Scaffold from Easily Available Starting Materials Shengming Ma*, Ping Lu, Lianghua Lu, Hairong Hou, Jiemin Wei, Qiwen He, Zhenhua Gu, Xuefeng Jiang, and Xing Jin Angew. Chem. Int. Ed. 2005, 44, 5275-5278.

24. 1,4-Migration of Rhodium and Palladium in Catalytic Organometallic Reactions Shengming Ma* and Zhenhua Gu Angew. Chem. Int. Ed. 2005, 44, 7512-7517.

25. Gold-Catalyzed Cyclization of Enynes Shengming Ma, Shichao Yu, Dr., Zhenhua Gu Angew. Chem. Int. Ed. 2006, 45, 200-203.

26. Pd(OAc)2-Catalyzed Coupling-Cyclization of 2,3-Allenoic Acids and Methyl Propiolate: An Unexpected p-Bond Migration Proceeds Through Double 1,7-Hydrogen Shifts *Zhenhua Gu and Shengming Ma* Angew. Chem. Int. Ed. 2006, 45, 6002-6005.

27. Pd(Ar-BIAN)(Alkene)-Catalyzed Highly Chemo-, Positional- and Stereo-selective Semi-Hydrogenation of 1,2-Allenylphosphonates and Related Compounds Hao Guo, Zilong Zheng, Fei Yu, Shengming Ma*, Alexandre Holuigue, Dorette S. Tromp, and Cornelis J. Elsevier,* Yihua Yu Angew. Chem. Int. Ed. 2006, 45, 4997-5000.

28. Controllable [2+2]-Cycloadditions of 1,5-Bisallenyl-Substituted Compounds Shengming Ma*, Xuefeng Jiang, and Xin Cheng Angew. Chem. Int. Ed. 2006, 45, 8009-8013.

29. Highly Selective Thiiranation of 1,2-Allenylic Sulfones with Br2 and Na2S2O3. Mechanistic Study and Asymmetric Synthesis of Alkylidenethiiranes Chao Zhou, Chunling Fu,* and Shengming Ma* Angew. Chem. Int. Ed. 2007, 46, 4379-4381.

30. Pd(PPh3)4-Catalyzed Diastereoselective Synthesis of Four-membered trans-1,2-Diazetidines from 2,3-Allenyl Hydrazines and Aryl Halides Xin Cheng and Shengming Ma Angew. Chem. Int. Ed. 2008, 47, 4581-4583.

31. An Efficient Approach to 1,5,7,8,9-Pentahydrocyclopenta[h]-2-benzopyran-3-one Derivatives via Palladium-catalyzed Tandem Reaction of 2,7-Alkadiynylic Carbonates with 2,3-Allenoic Acids Xiongdong Lian and Shengming Ma* Angew. Chem. Int. Ed. 2008, 47, 8255-8258.

32. Recent Advances on Asymmetric Synthesis via Metal-Catalyzed Enantioselective Allylation Reaction Zhan Lu and Shengming Ma* Angew. Chem. Int. Ed. 2008, 46, 258-297.

33. Highly Regio- and Stereoselective Double Michael Addition-Cyclization of 2,3-Allenoates with Organozinc Compounds. An Efficient Synthesis of 5-Benzylidenecyclohex-2-enones Zhan Lu, Guobi Chai, and Shengming Ma* Angew. Chem. Int. Ed. 2008, 47, 6045-6048.

34. Palladium-Catalyzed Three-Component Cascade Cyclization Reaction of Bisallenes with Propargylic Carbonates and Organoboronic Acids: Efficient Construction of cis-Fused Bicyclo[4.3.0]nonenes Wei Shu, Guochen Jia, and Shengming Ma* Angew. Chem. Int. Ed. 2009, 48, 2788-2791.