王新平 研究员  

中国科学院上海有机化学研究所 

金属有机化学国家重点实验室　 

上海市零陵路345号，200032 

电话: +86 21 54925602 

邮箱: xpwang@sioc.ac.cn 

网址:http:// www.sioc.cas.cn/xpwang/
教育：

1993/9 - 1997/6，四川大学，化学，学士，导师：陈耀强 教授  

1997/9 - 2000/6，兰州大学，化学，硕士，导师：曾正志 教授  

2001/9 - 2007/6，加拿大新布伦瑞克大学，化学，博士，导师：Jack Passmore 教授 
工作经历：

2007/11 - 2010/10，加州大学戴维斯分校，化学，博士后，导师：Philip P. Power 教授 

2010/11 - 2012/3，南京大学，化学化工学院，配位化学国家重点实验室，副教授 

2012/4 - 2023/2，南京大学，化学化工学院，配位化学国家重点实验室，教授 

2022/7 - 至今，中国科学院上海有机化学研究所，金属有机化学国家重点实验室，研究员  
研究领域：

主族元素化学，自由基化学，金属有机化学，小分子活化  

获奖及荣誉： 

中国科学院率先行动高层次人才计划A类（2022） 

国家级人才项目领军人才（2019） 

科技部中青年科技创新领军人才（2016） 

教育部长江学者奖励计划特聘教授（2015） 

国家杰出青年科学基金 （2015） 

江苏省杰出青年科学基金（2014） 

江苏省双创计划（2013） 

教育部新世纪优秀人才支持计划 (2012) 

国家级海外青年人才计划 (2011) 

南京大学优秀青年骨干教师计划 (2011) 

教育部国家优秀自费留学生奖学金 (2006) 
职务：
课题组长，金属有机化学国家重点实验室副主任

代表论著： 

1.  X. Dong, Q. Luo, Y. Zhao, T. Wang, Q. Sun, R. Pei, Y. Zhao, Y. Zheng* and X. Wang*. A Dynamic Triradical：Synthesis, Crystal Structure and Spin Frustration. J. Am. Chem. Soc. 2023,  DOI:10.1021/jacs.3c04692.

2.  M. Liu, X. Yang, Q. Sun, T. Wang, R. Pei, X. Yang, Y. Zhao, L. Zhao,* G. Frenking,* X. Wang,* Lewis Acid-Mediated Radical Stabilization and Dynamic Covalent Bonding: Tunable, Reversible and Photocontrollable. Angew. Chem. Int. Ed. 2023, published online, DOI:10.1002/anie.202300068.   

3.  W. Wang, X. Ma, M. Liu, S. Tang, X. Ding, Y. Zhao, Y. Tan,* M. Kertesz,* X. Wang,* A Triply Negatively Charged Nanographene Bilayer with Spin Frustration.Angew. Chem. Int. Ed. 2022,published online,DOI:10.1002/anie.202217788. 

4.  J. Wang, H. Cui, H. Ruan, Y. Zhao, Y. Zhao, L. Zhang,* X. Wang,* The Lewis Acid-Induced Formation of a Stable Diradical with an Intra Molecular Ion Pairing State. J. Am. Chem. Soc. 2022, 144, 18, 7978-7982. 

5.  Z. Feng, S. Tang, Y. Su, X. Wang,* Recent Advances in Stable Main Group Element Radicals: Preparation and Characterization. Chem. Soc. Rev. 2022, 51, 5930-5973.  

6.  W. Yang, L. Zhang, D. Xiao, R. Feng, W. Wang, Y. Zhao, L. Zhao,* G. Frenking,* X. Wang,* A Diradical Based on Odd-Electron σ-Bonds. Nat. Commun. 2020, 11:1-8. DOI: 10.1038/s41467-020-17303-4. Highlighted in Nat. Rev. Chem. (Bonding Electrons Happy with Single Life. Nat. Rev. Chem. 2020, 4, 438). 

7.  D. Tuo, C. Chen, H. Ruan, Q. Wang, Y. Ao, X. Wang,* D. Wang,* Magnetic Multistability in an Anion Radical Pimer. Angew. Chem. Int. Ed. 2020, 59, 14040-14043. 

8.  S. Tang, L. Zhang, H. Ruan, Y. Zhao, X. Wang,* A Magnetically Robust Triplet Ground State Sulfur- Hydrocarbon Diradical Dication. J. Am. Chem. Soc. 2020, 142, 7340-7344. 

9.  C. Chen, H. Ruan, Z. Feng, Y. Fang, Y. Zhao, Y. Su,* X. Wang,* Crystalline Diradical Dianions of Azaacenes. Angew. Chem. Int. Ed. 2020, 59, 11794-11799. 

10.  Z. Feng, Y. Fang, H. Ruan, Y. Zhao, G. Tan,* X. Wang,* Stable Radical Cation and Dication of an N-Heterocyclic Carbene Stabilized Digallene: Synthesis, Characterization and Reactivity，Angew. Chem. Int. Ed. 2020, 59, 6769-6774. 

11.  S. Tang, H. Ruan, R. Feng, Y. Zhao, G. Tan, L. Zhang,* X. Wang*, Tunable Reduction of 2,4,6-Tri(4-pyridyl)-1,3,5-Triazine: from Radical Anion to Diradical Dianion to Radical-Contained Metal-Organic Framework,Angew. Chem. Int. Ed. 2019, 58, 18224-18229. 

12.  M. Mondal, L. Zhang, Z. Feng, S. Tang, R. Feng, Y. Zhao, G. Tan,* H. Ruan,* X. Wang*, Tricoordinate Nontrigonal Pnictogen-Centered Radical Anions: Isolation, Characterization and Reactivity，Angew. Chem. Int. Ed. 2019, 58, 15829-15833. 

13.  R. Feng, L. Zhang, H. Ruan, Y. Zhao, G. Tan* and X. Wang*, A Main-Group Element Radical Based One-Dimensional Magnetic Chain, Angew. Chem. Int. Ed. 2019, 58, 6084-6088. 

14.  W. Wang, C. Chen, C. Shu, S. Rajca, X. Wang,* A. Rajca,* S = 1 Tetraazacyclophane Diradical Dication with Robust Stability: A Case of Low-Temperature One-Dimensional Antiferromagnetic Chain, J. Am. Chem. Soc. 2018, 140, 7820？7826. 

15.  W. Wang, C. Xu, Y. Fang, Y. Zhao, J. Li,* X. Wang,* An Isolable Diphosphene Radical Cation Stabilized by Three-Center Three-Electron π-Bonding with Chromium: End-On versus Side-On Coordination, Angew .Chem. Int. Ed. 2018, 57, 9563–9568. 

16.  T. Li, H. Wei, Y. Fang, L. Wang, S. Chen, Z. Zhang, Y. Zhao, G. Tan,* X. Wang,* Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies, Angew. Chem. Int. Ed.2017, 56, 632. 

17.  L. Wang, L. Zhang, Y. Fang, J. Li, C. Chen, Y. Zhao, Y. Song, L. Deng, G. Tan,* X. Wang,* P. P. Power,* Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion, J. Am. Chem. Soc. 2017, 139, 17723. 

18.  G. Tan, X. Wang,* Isolable Bis(triarylamine) Dications: Analogues of Thiele’s, Chichibabin’s, and Müller’s Hydrocarbons, Acc. Chem. Res. 2017, 50, 1997. 

19.  W. Wang, J. Li, L. Yin, Y. Zhao, Z. Ouyang, X. Wang,* Z. Wang,* Y. Song,* P. P. Power,* Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared Absorbing Dye to a Single-Molecule Magnet, J. Am. Chem. Soc. 2017, 139, 12069. 

20.  G. Tan, J. Li, Li Zhang, C. Chen, Y. Zhao, X. Wang,* Y. Song,* Y. Zhang,* M. Driess,* The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition Metal Complexes, Angew. Chem. Int. Ed. 2017, 56, 12741. 

21.  T. Li, G. Tan, D. Shao, J. Li, Z. Zhang, Y. Song, Y. Sui, S. Chen, Y. Fang, X. Wang,* Magnetic Bistability in a Discrete Organic Radical, J. Am. Chem. Soc. 2016, 138, 10092-10095. 

22.  G. Tan, S. Li, S. Chen, Y. Sui, Y. Zhao, X. Wang,* Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion. J. Am. Chem. Soc. 2016, 138, 6735-6738. 

23.  X. Zheng, X. Wang, Z. Zhang, Y. Sui, X. Wang,* P. P. Power,* Access to Stable Metalloradicals with Unsupported and Isomeric Metal-Metal Hemi-Bonds, Angew. Chem. Int. Ed. 2015, 54, 9084–9087 (VIP Paper). 

24. Y. Su, X. Wang, Y. Li, Y. Song, Y. Sui, X. Wang,* Nitrogen Analogues of Thiele’s Hydrocarbon：Closed-Shell vs Open-Shell in the Ground State, Angew. Chem. Int. Ed. 2015, 54, 1634–1637. 

25.  S. Zhang, X. Wang, Y. Sui,* X. Wang,* Odd-Electron Bonded Sulfur Radical Cations: X-ray Structural Evidence of a Sulfur-Sulfur Three-Electron σ–Bond, J. Am. Chem. Soc. 2014, 136, 14666–14669. Highlighted by C&E News (“When Three Electrons Are Not a Crowd”, Oct. 27, 2014) 

26.  X. Pan, X. Wang, Y. Zhao, Y. Sui, and X. Wang,* A Crystalline Phosphaalkene Radical Anion, J. Am. Chem. Soc. 2014, 136, 9834–9837. 

27.  S. Zhang, X. Wang, Y. Su, Y. Qiu, Z. Zhang, and X. Wang,* Isolation and Reversible Dimerization of a Selenium–Selenium Three–Electron σ–Bond, Nat. Commun. 2014, 5, 4127. 

28.  Y. Su, X. Zheng, X. Wang, X. Zhang, Y. Sui, and X. Wang,* Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions, J. Am. Chem. Soc. 2014, 136, 6251–6254. 

29.  Y. Su, X. Wang, X. Zheng, Z. Zhang, Y. Song, Y. Sui, Y. Li, and X. Wang,* Tuning Ground States of Bis(triphenylamine)benzidine Dications by Substituent Effect: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State, Angew. Chem. Int. Ed. 2014, 53, 2857–2861. 

30.  X. Zheng, X. Wang, Y. Qiu, Y. Li, C. Zhou, Y. Sui, Y. Li, J. Ma, and X. Wang*, One-Electron Oxidation of an Organic Molecule by B(C6F5)3; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid, J. Am. Chem. Soc. 2013, 135, 14912–14915. 

31.  X. Pan, Y. Su, X. Chen, Y. Zhao, Y. Li, J. Zuo, and X. Wang,* Stable Tetraaryldiphosphine Radical Cation and Dication, J. Am. Chem. Soc. 2013, 135, 5561–5564. 

32.  X. Pan, X. Chen, T. Li, Y. Li, and X. Wang,* Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations, J. Am. Chem. Soc. 2013, 135, 3414–3417. 

33.  X. Chen, X. Wang, Z. Zhou, Y. Li, Y. Sui, J. Ma, X. Wang,* P. P. Power,* Reversible σ-Dimerizations of Persistent Organic Radical Cations, Angew. Chem. Int. Ed. 2013, 52, 589–592. 

34.  X. Chen, X. Wang, Y. Sui,Y. Li, J. Ma,* J. Zuo and X. Wang,* Synthesis,Characterization and Structures of a Persistent Aniline Radical Cation, Angew. Chem. Int. Ed. 2012, 51,11878–11881. 

35.  X. Wang,* P. P. Power,* Structural Characterization, Infrared Spectroscopy and Theoretical Calculations for B(C6F5)3 Stabilized Benzene-Ammonia and Benzene-Water Complexes, Angew. Chem. Int. Ed. 2011, 50, 10965–10968. 

独立工作前： 

36.  X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*, A ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr'GeGeAr']+SbF6？ and [Ag2Ar'GeGe(F)Ar']+SbF6- (Ar'=C6H3-2,6(C6H3-2,6-Pri2)2), J. Am. Chem. Soc. 2010, 132, 13150 - 13151. 

37.  X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond, Angew. Chem. Int. Ed. 2010, 49, 4593 - 4597. 

38.  X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P. P. Power*, An unsymmetric oxo/imido bridged germanium-centered singlet diradicaloid, J. Am. Chem. Soc. 2009, 131, 14164 – 14165. 

39.  X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*. Room-temperature reaction of carbon monoxide with a stable diarylgermylene, J. Am. Chem. Soc., 2009, 131, 6912 - 6913. 

40.  T. S. Cameron (X-ray), J. Passmore* (Supervisor), X. Wang. The Preparation and X-ray Crystal Structure of [(AgI2)n]MF6 (M=Sb, As): Diiodine Acting as a Donor in the Planar Polymeric [(AgI2)n]n+, Angew Chem. Int. Ed. 2004, 43, 1995 – 1998. (作者按姓氏第一个英文字母顺序排列). 

　　Selected as a textbook example：Housecroft & Sharpe，Inorg. Chem. 3rd ed，Pearson，2006，p542. 

41.  A. Decken (X-ray), J. Passmore* (Supervisor), X. Wang. Cyclic dimethylsiloxanes as pseudo crown ethers: Syntheses and characterization of Li(Me2SiO)5[Al{OC(CF3)3}4], Li(Me2SiO)6[Al{OC(CF3)3}4], and Li(Me2SiO)6[Al{OC(CF3)3Ph}4], Angew. Chem. Int. Ed. 2006, 45, 2773 - 2777. (作者按姓氏第一个英文字母顺序排列). 

42.  Highlighted in C&E News (April 10, 2006, P54) and Angew Chem. Int. Ed. ( 2007, 46, 4610 - 4613).